Secure pressure cooker lid and raise heat to high heat.
Once you hear the pressure cooker hissing, lower heat to low and leave to cook for 2-4 hours; the longer, the better.
After at least 2 hours, release all of the pressure from the pressure cooker until the float valve drops and you no longer hear steam escaping. Taste the vegetable stock. You're looking for a rich vegetable flavor; if it tastes like watered-down tea, you need to cook it longer.
When your vegetable stock is ready, place a colander or a large fine-mesh strainer into another large pot or mixing bowl and pour out the contents from your pressure cooker into the strainer. Lift the strainer, containing all of the vegetable scraps, from the large pot or mixing bowl and hold it just above, filtering out the last drops of stock.
You should only have vegetable stock left in the pot or bowl. Set aside to cool. Use immediately, refrigerate for up to 5 days, or store in the freezer for no longer than 3 months.